A DC-DC converter including a Pulse Width Modulation (PWM) controller for converting an input voltage into an output voltage is provided. The PWM controller includes an error amplifier, a comparator, a PWM generator and a ramp generator. The error amplifier generates an error signal according to a difference between a reference voltage and the output voltage. The comparator compares the error signal with a ramp signal to generate a trigger signal. The PWM generator generates a PWM signal with a fixed turn-on time, wherein a frequency of the PWM signal is adjusted according to the trigger signal, the input and output voltages. The ramp generator generates the ramp signal according to the PWM signal, the input voltage and the output voltage.