发明授权
US08431742B2 Method for producing dodeca-2,10-diene-1,12-dicarboxylic acid or 1,12-dodecane-dicarboxylic acid by way of ring-opening cross metathesis (ROCM) of cyclooctene with acrylic acid
有权
通过环辛烯与丙烯酸的开环交叉复分解（ROCM）制备十二碳-2,10-二烯-1,12-二羧酸或1,12-十二烷二羧酸的方法
- 专利标题： Method for producing dodeca-2,10-diene-1,12-dicarboxylic acid or 1,12-dodecane-dicarboxylic acid by way of ring-opening cross metathesis (ROCM) of cyclooctene with acrylic acid
- 专利标题（中）： 通过环辛烯与丙烯酸的开环交叉复分解（ROCM）制备十二碳-2,10-二烯-1,12-二羧酸或1,12-十二烷二羧酸的方法
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申请号： US12922807申请日： 2009-04-16
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公开(公告)号： US08431742B2公开(公告)日： 2013-04-30
- 发明人: Peter Hannen , Martin Roos , Harald Haeger
- 申请人： Peter Hannen , Martin Roos , Harald Haeger
- 申请人地址： DE Essen
- 专利权人： Evonik Degussa GmbH
- 当前专利权人： Evonik Degussa GmbH
- 当前专利权人地址： DE Essen
- 代理机构： Oblon, Spivak, McClelland, Maier & Neustadt, L.L.P.
- 优先权： DE102008002092 20080530
- 国际申请： PCT/EP2009/054519 WO 20090416
- 国际公布： WO2009/144089 WO 20091203
- 主分类号： C07C51/353
- IPC分类号： C07C51/353 ; C07C51/43 ; C07C51/44 ; C07C57/13
摘要：
The invention relates to a method for producing 1,2-dodeca-2,10-diene diacid and 1,12-dodecanoic acid whereby cyclooctene and acrylic acid are reacted with a ruthenium catalyst by way of a metathesis reaction at high substrate concentrations until the reaction takes place in substance, the resulting unsaturated dicarboxylic acid being precipitated and being hydrated in a second reaction step.
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