发明授权
- 专利标题: Modified acidic ion-exchange resin and method for preparing bisphenol
- 专利标题(中): 改性酸性离子交换树脂及其制备方法
-
申请号: US12875016申请日: 2010-09-02
-
公开(公告)号: US08436055B2公开(公告)日: 2013-05-07
- 发明人: Takashi Terajima , Toshihiro Takai , Kenji Fujiwara
- 申请人: Takashi Terajima , Toshihiro Takai , Kenji Fujiwara
- 申请人地址: JP Tokyo
- 专利权人: Mitsui Chemicals, Inc.
- 当前专利权人: Mitsui Chemicals, Inc.
- 当前专利权人地址: JP Tokyo
- 代理机构: Birch, Stewart, Kolasch & Birch, LLP
- 优先权: JP2003-339944 20030930; JP2004-133344 20040428
- 主分类号: C08J5/20
- IPC分类号: C08J5/20
摘要:
The present invention provides an ion-exchange resin catalyst, as a catalyst for preparing bisphenol from phenol compounds and ketone, which has a higher selectivity to bisphenol and a longer life time, as compared to a conventional ion-exchange resin, and a method for preparing the same.The present invention also provides a method for preparing bisphenol comprising reacting phenol compounds with ketone, wherein the modified acidic ion-exchange resin in which at least one kind of cationic compound selected from the following (a), (b), (c) and (d) ionically binds to an acidic functional group, is used as a catalyst: (a) a quaternary phosphonium ion, (b) a quaternary ammonium ion, (c) a bis(phosphoranylidene) ammonium ion, and (d) an N-substituted nitrogen-containing aromatic cation.
公开/授权文献
信息查询