发明授权
- 专利标题: Method for producing N,N-substituted-1,3-propandiamines
- 专利标题(中): 制备N,N-取代-1,3-丙二胺的方法
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申请号: US12991767申请日: 2009-05-11
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公开(公告)号: US08461391B2公开(公告)日: 2013-06-11
- 发明人: Martin Ernst , Johann-Peter Melder , Christof Wilhelm Wigbers
- 申请人: Martin Ernst , Johann-Peter Melder , Christof Wilhelm Wigbers
- 申请人地址: DE
- 专利权人: BASF SE
- 当前专利权人: BASF SE
- 当前专利权人地址: DE
- 代理机构: Novak Druce Connolly Bove + Quigg LLP
- 优先权: EP08156092 20080513; EP08168393 20081105
- 国际申请: PCT/EP2009/055655 WO 20090511
- 国际公布: WO2009/138377 WO 20091119
- 主分类号: C07C209/60
- IPC分类号: C07C209/60
摘要:
The present invention relates to a process for preparing N,N-substituted 1,3-propanediamine by a) reacting secondary amine with acrolein at a temperature of from (−50) to 100° C. and a pressure of from 0.01 to 300 bar, and b) reacting the reaction mixture obtained in stage a) with hydrogen and ammonia in the presence of a hydrogenation catalyst at a temperature of from 40 to 400° C. and a pressure of from 1 to 400 bar, wherein the molar ratio of secondary amine to acrolein in stage a) is 2:1 or more and the hydrogenation catalyst used in stage b) comprises cobalt. In a preferred embodiment, acrolein which has been obtained from glycerol based on renewable raw materials is used. The invention further relates to the use of N,N-dimethyl-1,3-propanediamine (DMAPA) based on renewable raw materials as a feedstock for lubricant soaps and other detergents, coagulants, polymers and comb polymers. In a further preferred embodiment, stage b) is performed in the presence of water.
公开/授权文献
- US20110060166A1 METHOD FOR PRODUCING N,N-SUBSTITUTED-1,3-PROPANDIAMINES 公开/授权日:2011-03-10
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