发明授权
- 专利标题: Photosensitizer and photovoltaic device
- 专利标题(中): 光敏剂和光电器件
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申请号: US12934447申请日: 2009-03-25
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公开(公告)号: US08471018B2公开(公告)日: 2013-06-25
- 发明人: Noriyo Yamanaka , Masaki Minami , Tsutomu Nakamura , Hideki Masuda , Zhengzhe Jin
- 申请人: Noriyo Yamanaka , Masaki Minami , Tsutomu Nakamura , Hideki Masuda , Zhengzhe Jin
- 申请人地址: JP Tokyo JP Aichi
- 专利权人: JX Nippon Oil & Energy Corporation,Nagoya Institute of Technology
- 当前专利权人: JX Nippon Oil & Energy Corporation,Nagoya Institute of Technology
- 当前专利权人地址: JP Tokyo JP Aichi
- 代理机构: Panitch Schwarze Belisario & Nadel LLP
- 优先权: JP2008-080977 20080326; JP2008-115831 20080425; JP2008-290990 20081113
- 国际申请: PCT/JP2009/001324 WO 20090325
- 国际公布: WO2009/119085 WO 20091001
- 主分类号: C07F15/00
- IPC分类号: C07F15/00 ; H01L51/00
摘要:
Disclosed is a novel photosensitizer that can absorb light in a wide visible light region and in the case of a very thin film form, can enhance a light absorption efficiency by virtue of a large light absorption coefficient. The photosensitizer is used for metal oxide semiconductor electrodes and comprises a metal complex represented by a general formula ML1L2X2, wherein M is a group 8 transition metal of the periodic table, Xs are each independently a halogen atom, a cyano group, a thiocyanate group, an isothiocyanate group, an isocyanate group, an isocyanide group or a hydroxyl group, or a bidentate ligand in the case where Xs are bonded to one another, L1 and L2 are each a ligand having an aromatic ring, and either L1 or L2 has a functional group having a COOH group or PO(OH)2, and when the photosensitizer is adsorbed on a metal oxide semiconductor electrode via ligands L1 and L2, the difference ΔL between the energy levels of ligands L1 and L2 in their excited states, calculated in accordance with a GAUSSIAN03 quantum chemistry calculation program is 0.25 eV or more.
公开/授权文献
- US20110108117A1 PHOTOSENSITIZER AND PHOTOVOLTAIC DEVICE 公开/授权日:2011-05-12
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