发明授权
- 专利标题: Process to produce polyalphaolefins
- 专利标题(中): 生产聚α-烯烃的方法
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申请号: US11832287申请日: 2007-08-01
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公开(公告)号: US08513478B2公开(公告)日: 2013-08-20
- 发明人: Margaret M. Wu , Mark P. Hagemeister , Norman Yang
- 申请人: Margaret M. Wu , Mark P. Hagemeister , Norman Yang
- 申请人地址: US TX Houston
- 专利权人: ExxonMobil Chemical Patents Inc.
- 当前专利权人: ExxonMobil Chemical Patents Inc.
- 当前专利权人地址: US TX Houston
- 代理商 Catherine L. Bell; Nancy T. Krawczyk; Leandro Arechederra, III
- 主分类号: C07C2/22
- IPC分类号: C07C2/22
摘要:
Liquid poly-alpha-olefins having a KV100 of 2 to 6000 cSt, 20 weight percent dimer or less and a viscosity index of 60 or more are obtained by contacting in a reaction zone, in the presence of from 0 to 60 psi hydrogen, C3 to C20 alpha-olefin monomers with a non-coordinating anion activator, a single bridged meso-metallocene transition metal compound having less than about 35 wt % racemic isomer, and a co-activator. The molar ratio of activator to meso-metallocene is from 10:1 to 0.1:1, and the alpha-olefin monomers in the feed components are present in at least 20 wt % or more based upon the weight of the meso-metallocene, non-coordinating anion activator, co-activator, monomers, and solvent or diluent. The productivity of the process is at least 50,000 g of total product per gram of transition metal compound and no more than 5% monomer is converted from olefin to alkane.
公开/授权文献
- US20090036725A1 Process To Produce Polyalphaolefins 公开/授权日:2009-02-05
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