发明授权
US08546499B2 Linear low density polyethylene with uniform or reversed comonomer composition distribution
有权
具有均匀或反相共聚单体组成分布的线性低密度聚乙烯
- 专利标题: Linear low density polyethylene with uniform or reversed comonomer composition distribution
- 专利标题(中): 具有均匀或反相共聚单体组成分布的线性低密度聚乙烯
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申请号: US13318101申请日: 2010-04-26
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公开(公告)号: US08546499B2公开(公告)日: 2013-10-01
- 发明人: Thomas Garroff , Paivi Waldvogel , Kallio Kalle , Virginie Eriksson , Aki Aittola , Esa Kokko
- 申请人: Thomas Garroff , Paivi Waldvogel , Kallio Kalle , Virginie Eriksson , Aki Aittola , Esa Kokko
- 申请人地址: AT Vienna
- 专利权人: Borealis AG
- 当前专利权人: Borealis AG
- 当前专利权人地址: AT Vienna
- 代理机构: Roberts Mlotkowski Safran & Cole, P.C.
- 优先权: EP09159144 20090430
- 国际申请: PCT/EP2010/055519 WO 20100426
- 国际公布: WO2010/125022 WO 20101104
- 主分类号: C08F4/44
- IPC分类号: C08F4/44
摘要:
Ziegler-Natta catalyzed linear low density polyethylene which satisfies the following conditions:a) a density, according to ISO 1183, of from 900 to 925 kg/m3,b) a C4-C10-comonomer content, determined by Fourier transform infrared spectroscopy, of 1 to 16 wt %c) a weight average molecular weight Mw, determined by gel permeation chromatography, of at least 200 000,d) wherein the linear low density polyethylene comprises, by Crystallisation Analysis Fractionation (CRYSTAF) an amorphous fraction soluble at a temperature below 30° C. of at most 10 wt % and a fraction crystallising between 60 to 75° C. of at least 35 wt % ande) by temperature rising elution fractionation (TREF) analysis, at least 70 wt % of a crystallising polymer component having an elution temperature range from 60° C. to 94° C. and less than 10 wt % of a crystallising polymer component having an elution temperature range from 30° C. to 60° C. and,f) by Gel Permeation chromatography coupled with Fourier transform infrared spectroscopy detector (GPC-FTIR), a substantially constant short chain branching profile across the molecular weight distribution (MWD) org) by Gel Permeation chromatography coupled with Fourier transform infrared spectroscopy instruments (GPC-FTIR), a reverse short chain branching profile across the molecular weight distribution (MWD),the linear low density polyethylene being produced in the presence of a special Ziegler-Natta procatalyst and a halogenated aluminium alkyl cocatalyst of the formula (IV) (C1-C4- alkyl)m-Al-X3−m, wherein X is chlorine, bromine, iodine or fluorine and m is 1 or 2.
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