In the field of communications, a session transfer method and a User Equipment (UE) are provided, so as to solve the problem that when a UE is involved in a voice session and a video session at the same time, session transfer cannot be performed. The technical solution according to the present invention includes: determining a session in an active state among a video session and a voice session; and initiating transfer of the session in the active state, so that a network side transfers the session in the active state to a Circuit Switched (CS) domain, and transfers a session in an inactive state among the video session and the voice session. The session transfer method and the UE may be applied in a radio communication network.