Invention Grant
- Patent Title: Metallocene catalysts and their use in polymerization processes
- Patent Title (中): 茂金属催化剂及其在聚合工艺中的应用
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Application No.: US12739308Application Date: 2008-10-09
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Publication No.: US08598287B2Publication Date: 2013-12-03
- Inventor: Chi-I Kuo , Dongming Li , Ching-Tai Lue , Francis C. Rix , Mark G Goode , Daniel P. Zilker, Jr. , Tae Hoon Kwalk
- Applicant: Chi-I Kuo , Dongming Li , Ching-Tai Lue , Francis C. Rix , Mark G Goode , Daniel P. Zilker, Jr. , Tae Hoon Kwalk
- Applicant Address: US TX Houston
- Assignee: Univation Technologies, LLC
- Current Assignee: Univation Technologies, LLC
- Current Assignee Address: US TX Houston
- Agent Jennifer A. Schmidt; Kristina Leavitt
- International Application: PCT/US2008/011607 WO 20081009
- International Announcement: WO2009/054889 WO 20090430
- Main IPC: C08F4/6592
- IPC: C08F4/6592 ; C08F4/643 ; C08L23/14

Abstract:
A process for polymerizing olefin(s) utilizing a cyclic bridged metallocene catalyst system to produce polymers with improved properties is provided. The catalyst system may include a cyclic bridged metallocene, LA(R′SiR′)LBZrQ2, activated by an activator, the activator comprising aluminoxane, a modified aluminoxane, or a mixture thereof, and supported by a support, where: LA and LB are independently an unsubstituted or a substituted cyclopentadienyl ligand bonded to Zr and defined by the formula (C5H4-dRd), where R is hydrogen, a hydrocarbyl substituent, a substituted hydrocarbyl substituent, or a heteroatom substituent, and where d is 0, 1, 2, 3 or 4; LA and LB are connected to one another with a cyclic silicon bridge, R′SiR′, where R′ are independently hydrocarbyl or substituted hydrocarbyl substituents that are connected with each other to form a silacycle ring; and each Q is a labile hydrocarbyl or a substituted hydrocarbyl ligand.
Public/Granted literature
- US20100298511A1 METALLOCENE CATALYSTS AND THEIR USE IN POLYMERIZATION PROCESSES Public/Granted day:2010-11-25
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