发明授权
- 专利标题: Process for the preparation of N-vinylcarboxamides
- 专利标题(中): 制备N-乙烯基甲酰胺的方法
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申请号: US13139521申请日: 2009-12-04
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公开(公告)号: US08598385B2公开(公告)日: 2013-12-03
- 发明人: Manfred Winter , Hagen Weigl , Andreas Kramer
- 申请人: Manfred Winter , Hagen Weigl , Andreas Kramer
- 申请人地址: DE Ludwigshafen
- 专利权人: BASF SE
- 当前专利权人: BASF SE
- 当前专利权人地址: DE Ludwigshafen
- 代理机构: Oblon, Spivak, McClelland, Maier & Neustadt, L.L.P.
- 优先权: EP08171677 20081215
- 国际申请: PCT/EP2009/066387 WO 20091204
- 国际公布: WO2010/072543 WO 20100701
- 主分类号: C07C231/06
- IPC分类号: C07C231/06
摘要:
Process for the preparation of N-vinylcarboxamides by pyrolysis of a compound of the formula CH3—CH(CN)—N(R)—CO—R1 (I), in which R and R1 are H or C1- to C6-alkyl, in the presence of solids which are doped with alkali metal or alkaline earth metal ions, under reduced pressure at a temperature of from 330 to 750° C. with elimination of hydrogen cyanide, cooling, separation and isolation of the reaction products, a solid arranged in a tubular reactor being treated at a temperature in the range from 0 to 250° C. with a solution of an alkali metal and/or alkaline earth metal base, the solution being discharged, the remaining solvent which adheres to the catalyst thus obtainable being evaporated and said catalyst then being heated to a temperature of at least 380° C. for activation.
公开/授权文献
- US20110245539A1 PROCESS FOR THE PREPARATION OF N-VINYLCARBOXAMIDES 公开/授权日:2011-10-06