Invention Grant
- Patent Title: High vinyl terminated propylene based oligomers
- Patent Title (中): 高乙烯基封端的丙烯基低聚物
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Application No.: US13670085Application Date: 2012-11-06
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Publication No.: US08653209B2Publication Date: 2014-02-18
- Inventor: Patrick Brant , Donna J. Crowther , Andrew G. Narvaez, Jr.
- Applicant: ExxonMobil Chemical Patents Inc.
- Applicant Address: US TX Houston
- Assignee: ExxonMobil Chemical Patents Inc.
- Current Assignee: ExxonMobil Chemical Patents Inc.
- Current Assignee Address: US TX Houston
- Agent Catherine L. Bell
- Main IPC: C08F4/64
- IPC: C08F4/64 ; C08F4/52 ; C08F4/76 ; C08F10/06

Abstract:
This invention relates to a co-oligomer having an Mn of 300 to 30,000 g/mol comprising 10 to 90 mol % propylene and 10 to 90 mol % of ethylene, wherein the oligomer has at least X % allyl chain ends, where: 1) X=(−0.94(mole % ethylene incorporated)+100), when 10 to 60 mole % ethylene is present in the co-oligomer, and 2) X=45, when greater than 60 and less than 70 mole % ethylene is present in the co-oligomer, and 3) X=(1.83*(mole % ethylene incorporated)−83), when 70 to 90 mole % ethylene is present in the co-oligomer. This invention also relates to a homo-oligomer, comprising propylene, wherein the oligomer has: at least 93% allyl chain ends, an Mn of about 500 to about 20,000 g/mol, an isobutyl chain end to allylic vinyl group ratio of 0.8:1 to 1.2:1.0, and less than 100 ppm aluminum. This invention also relates to a process of making homo-oligomer, comprising propylene, wherein the productivity is greater than 4500 g/mmol Hf (or Zr)/hour.
Public/Granted literature
- US20130066103A1 High Vinyl Terminated Propylene Based Oligomers Public/Granted day:2013-03-14
Information query
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