Invention Grant
- Patent Title: Solid-state polymerization of a liquid crystalline polymer
- Patent Title (中): 液晶聚合物的固态聚合
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Application No.: US13594912Application Date: 2012-08-27
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Publication No.: US08669341B2Publication Date: 2014-03-11
- Inventor: Kamlesh P. Nair , Steven D. Gray
- Applicant: Kamlesh P. Nair , Steven D. Gray
- Applicant Address: US KY Florence
- Assignee: Ticona LLC
- Current Assignee: Ticona LLC
- Current Assignee Address: US KY Florence
- Agency: Dority & Manning, P.A.
- Main IPC: C08G63/02
- IPC: C08G63/02 ; C08G64/00

Abstract:
A method for forming a high molecular weight thermotropic liquid crystalline polymer is provided. The method includes melt polymerizing two or more monomers in the presence of a unique aromatic amide oligomer to form a prepolymer, and then solid-state polymerizing the prepolymer to achieve a target molecular weight. The present inventors have discovered that a unique aromatic amide oligomer can be employed to help increase the “low shear” complex viscosity of the resulting solid-state polymerized composition. This allows for the attainment of higher than conventional “low shear” complex viscosity values and/or a substantial reduction in the solid-state polymerization time needed to achieve a target complex viscosity. In addition, the oligomeric flow aid can also accelerate the extent to which the “high shear” melt viscosity is increased during solid-state polymerization, which may also contribute to a substantial reduction in the solid-state polymerization time needed to achieve a certain molecular weight.
Public/Granted literature
- US20130053533A1 Solid-State Polymerization of a Liquid Crystalline Polymer Public/Granted day:2013-02-28
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