发明授权
- 专利标题: Process for working up an exhaust gas from a system for producing hydroxylamine or hydroxylammonium salts
- 专利标题(中): 从用于生产羟胺或羟铵盐的系统处理废气的方法
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申请号: US13876496申请日: 2011-09-27
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公开(公告)号: US08679436B2公开(公告)日: 2014-03-25
- 发明人: Arnd Garsuch , Alexander Panchenko , Sigmar Bräuninger , Jens Scheidel , Alfred Thome
- 申请人: Arnd Garsuch , Alexander Panchenko , Sigmar Bräuninger , Jens Scheidel , Alfred Thome
- 申请人地址: DE
- 专利权人: BASF SE
- 当前专利权人: BASF SE
- 当前专利权人地址: DE
- 代理机构: Novak Druce Connolly Bove + Quigg LLP
- 优先权: EP10184335 20100930
- 国际申请: PCT/EP2011/066781 WO 20110927
- 国际公布: WO2012/041859 WO 20120405
- 主分类号: B01D53/34
- IPC分类号: B01D53/34 ; B01D53/46 ; C07C215/00
摘要:
Process for working up an exhaust gas from a system for producing hydroxylamine or hydroxylammonium salts by catalytic reduction of nitrogen monoxide with hydrogen, the exhaust gas containing nitrogen monoxide, hydrogen, dinitrogen monoxide, nitrogen and ammonia. At least some of the hydrogen present in the exhaust gas is separated off from the exhaust gas by means of a gas-tight membrane-electrode assembly which comprises at least one selectively proton-conducting membrane, a retentate side, a permeate side, and, on each side of the membrane, at least one electrode catalyst, wherein, on the retentate side of the membrane, at least some of the hydrogen is oxidized to protons at the anode catalyst and the protons, after crossing the membrane, are, on the permeate side, at the cathode catalyst according to (I) reduced to hydrogen and/or (II) reacted with oxygen to form water, the oxygen originating from an oxygen-containing stream which is contacted with the permeate side.