发明授权
- 专利标题: Process for producing amide or lactam
- 专利标题(中): 生产酰胺或内酰胺的方法
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申请号: US12997287申请日: 2009-06-10
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公开(公告)号: US08680267B2公开(公告)日: 2014-03-25
- 发明人: Takahiro Iwahama , Tatsuya Nakano , Yasutaka Ishii
- 申请人: Takahiro Iwahama , Tatsuya Nakano , Yasutaka Ishii
- 申请人地址: JP Osaka-Shi
- 专利权人: Daicel Chemical Industries, Ltd.
- 当前专利权人: Daicel Chemical Industries, Ltd.
- 当前专利权人地址: JP Osaka-Shi
- 代理机构: Birch, Stewart, Kolasch & Birch, LLP
- 优先权: JP2008-152424 20080611
- 国际申请: PCT/JP2009/002627 WO 20090610
- 国际公布: WO2009/150838 WO 20091217
- 主分类号: C07D201/04
- IPC分类号: C07D201/04 ; C07D223/10 ; C07B61/00 ; C07D251/54
摘要:
A process produces an amide or lactam by subjecting an oxime compound to rearrangement in a solvent in the presence of: at least one catalyst selected from the group consisting of an aromatic compound (A1) containing a leaving group bound to a carbon atom constituting the aromatic ring, the aromatic ring including, as a constitutive atom thereof, a heteroatom or including, as a constitutive atom thereof, a carbon atom bound to an electron-withdrawing group, and a compound (A2) containing a structure of Formula (1): -G-LA (1) wherein G represents P, N, S, B or Si atom; and LA represents a leaving group, wherein G is bound to one or more atoms or groups in addition to LA; and a co-catalyst including a halogen-containing organic acid, to give the corresponding amide or lactam, wherein, when the aromatic compound (A1) alone is used as the catalyst, the solvent is at least one solvent selected typically from hydrocarbon solvents. The production process can yield amides or lactams simply in high yields without causing large amounts of by-products such as ammonium sulfate.
公开/授权文献
- US20110092699A1 PROCESS FOR PRODUCING AMIDE OR LACTAM 公开/授权日:2011-04-21