发明授权
US08697899B2 Methods for producing iron methacrylate and hydroxyalkyl methacrylate
有权
生产甲基丙烯酸铁和甲基丙烯酸羟烷基酯的方法
- 专利标题: Methods for producing iron methacrylate and hydroxyalkyl methacrylate
- 专利标题(中): 生产甲基丙烯酸铁和甲基丙烯酸羟烷基酯的方法
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申请号: US13822017申请日: 2011-12-26
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公开(公告)号: US08697899B2公开(公告)日: 2014-04-15
- 发明人: Naoshi Murata , Kuniyoshi Ogura , Takeshi Matsuo , Akira Yoshioka
- 申请人: Naoshi Murata , Kuniyoshi Ogura , Takeshi Matsuo , Akira Yoshioka
- 申请人地址: JP Tokyo
- 专利权人: Mitsubishi Rayon Co., Ltd.
- 当前专利权人: Mitsubishi Rayon Co., Ltd.
- 当前专利权人地址: JP Tokyo
- 代理机构: Oblon, Spivak, McClelland, Maier & Neustadt, L.L.P.
- 优先权: JP2010-290879 20101227
- 国际申请: PCT/JP2011/080011 WO 20111226
- 国际公布: WO2012/090905 WO 20120507
- 主分类号: C07F15/00
- IPC分类号: C07F15/00 ; C07C67/26
摘要:
There is provided a method for producing iron methacrylate being inexpensive, and being high in activity and selectivity and good in solubility to a reaction liquid when being used in production of a hydroxyalkyl methacrylate as a catalyst. The method for producing iron methacrylate for production of a hydroxyalkyl methacrylate according to the present invention includes subjecting a mixture of a metallic iron having an oxygen atom content by XRF analysis of the surface thereof of 6% by mass or lower, and methacrylic acid to a heat treatment at 95° C. or higher and lower than 110° C. for 100 to 600 min. The method for producing a hydroxyalkyl methacrylate according to the present invention includes reacting an alkylene oxide with methacrylic acid to produce the hydroxyalkyl methacrylate, wherein iron methacrylate produced by the method according to the present invention is used as a catalyst.
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