发明授权
US08704017B2 Continuous low-temperature process to produce trans-1-chloro-3,3,3-trifluoropropene
有权
连续低温法生产反式-1-氯-3,3,3-三氟丙烯
- 专利标题: Continuous low-temperature process to produce trans-1-chloro-3,3,3-trifluoropropene
- 专利标题(中): 连续低温法生产反式-1-氯-3,3,3-三氟丙烯
-
申请号: US13220212申请日: 2011-08-29
-
公开(公告)号: US08704017B2公开(公告)日: 2014-04-22
- 发明人: Konstantin A. Pokrovski , Daniel C. Merkel , Hsueh Sung Tung
- 申请人: Konstantin A. Pokrovski , Daniel C. Merkel , Hsueh Sung Tung
- 申请人地址: US NJ Morristown
- 专利权人: Honeywell International Inc.
- 当前专利权人: Honeywell International Inc.
- 当前专利权人地址: US NJ Morristown
- 代理商 Bruce O. Bradford
- 主分类号: C07C17/20
- IPC分类号: C07C17/20
摘要:
Disclosed is process for the production of (E) 1-chloro-3,3,3-trifluoropropene (HCFO-1233zd(E)) by conducting a continuous reaction without the use of a catalyst. Also disclosed is an integrated system for producing hydrofluoro olefins, particularly 1233zd(E). The manufacturing process includes six major unit operations: (1) a fluorination reaction of HCC-240fa (in continuous or semi-batch mode) using HF with simultaneous removal of by-product HCl and the product 1233zd(E); (2) recycle of unreacted HCC-240fa and HF together with under-fluorinated by-products back to (1); (3) separation and purification of by-product HCl; (4) separation of excess HF back to (1); (5) purification of final product, 1233zd(E); and (6) isomerization of by-product 1233zd(Z) to 1233zd(E) to maximize the process yield.
公开/授权文献
信息查询