发明授权
US08716175B2 Catalyst for producing ethylene oxide, process for producing the catalyst and process for producing ethylene oxide
有权
用于生产环氧乙烷的催化剂,用于生产催化剂的方法和用于生产环氧乙烷的方法
- 专利标题: Catalyst for producing ethylene oxide, process for producing the catalyst and process for producing ethylene oxide
- 专利标题(中): 用于生产环氧乙烷的催化剂,用于生产催化剂的方法和用于生产环氧乙烷的方法
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申请号: US12083876申请日: 2007-03-30
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公开(公告)号: US08716175B2公开(公告)日: 2014-05-06
- 发明人: Katsumi Nakashiro , Soichiro Yamada , Takanao Matsumoto
- 申请人: Katsumi Nakashiro , Soichiro Yamada , Takanao Matsumoto
- 申请人地址: JP Tokyo
- 专利权人: Mitsubishi Chemical Corporation
- 当前专利权人: Mitsubishi Chemical Corporation
- 当前专利权人地址: JP Tokyo
- 代理机构: Nixon & Vanderhye P.C.
- 优先权: JP2006-107329 20060410; JP2006-107330 20060410
- 国际申请: PCT/JP2007/000352 WO 20070330
- 国际公布: WO2007/116585 WO 20071018
- 主分类号: B01J23/48
- IPC分类号: B01J23/48
摘要:
There is provided a catalyst for producing ethylene oxide from ethylene which is composed of at least silver (Ag), cesium (Cs), rhenium (Re) and a carrier, and can be improved, in particular, in selectivity.The present invention relates to a catalyst for producing ethylene oxide from ethylene, comprising at least silver (Ag), cesium (Cs), rhenium (Re) and a carrier, said catalyst being produced by optionally pretreating the carrier to support an alkali metal thereon and then supporting Ag, Cs and Re on the carrier, wherein the carrier has a specific surface area of 0.6 to 3.0 m2/g and a weight ratio of a silicon (Si) content to a sodium (Na) content of 2 to 50 in terms of SiO2/Na2O; a content of Re in the catalyst is 170 to 600 ppm per 1 m2/g of the specific surface area of the carrier on the basis of a weight of the carrier; and a molar ratio of Cs to Re in the catalyst is 0.3 to 19.