发明授权
- 专利标题: Conversion of co-fed methane and low hydrogen content hydrocarbon feedstocks to acetylene
- 专利标题(中): 共同供应的甲烷和低含氢烃原料转化为乙炔
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申请号: US12323132申请日: 2008-11-25
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公开(公告)号: US08748686B2公开(公告)日: 2014-06-10
- 发明人: Paul F. Keusenkothen , Frank Hershkowitz
- 申请人: Paul F. Keusenkothen , Frank Hershkowitz
- 申请人地址: US TX Houston
- 专利权人: ExxonMobil Chemical Patents Inc.
- 当前专利权人: ExxonMobil Chemical Patents Inc.
- 当前专利权人地址: US TX Houston
- 主分类号: C07C2/78
- IPC分类号: C07C2/78 ; C07C4/04 ; C07C11/24
摘要:
A process and apparatus are provided to produce acetylene from a feed stream of low hydrogen content hydrocarbons such as coal by: (a) blending the hydrocarbons with methane to provide a blended mixture containing at least about 12.5 wt % atomic hydrogen; (b) partially combusting the blended mixture in a reactor in the presence of a source of oxygen to provide a partially combusted mixture at or above a temperature sufficient to produce methyl radicals; (c) maintaining the partially combusted mixture at or above the temperature for a residence time sufficient to produce a product stream containing enhanced yields of acetylene without significant formation of coke or coke precursors; (d) cooling the product stream to reduce the temperature of the product stream within a time sufficiently brief to substantially arrest any cracking reactions and provide a cooled product stream; and (e) recovering acetylene from the cooled product stream. The acetylene can be converted to ethylene by a conventional hydrogenation process.
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