The invention discloses a method and controller for processing data multiplication in a RAID system. Map tables are generated for all values in a field, respectively. The length of an XOR operation unit is chosen to be appropriate w bits (e.g., 332 bits or 64 bits). One or several XOR operation units form a multiplication unit of a data sector. When computing on-line, data in a disk drive of a disk array are performed with XOR operations in accordance with one of the map tables using an XOR operation unit as one unit while computing on the multiplication unit to obtain a product of multiplication. Making use of the RAID system established according to the disclosed method, only XOR operations are required to compute parity data or recover damaged user data. Moreover, several calculations can be performed simultaneously. Therefore, the efficiency of the RAID system can be effectively improved.