发明授权
- 专利标题: Continuous process for the carbonylation of ethylene
- 专利标题(中): 乙烯羰基化的连续工艺
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申请号: US13515585申请日: 2010-12-15
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公开(公告)号: US08785678B2公开(公告)日: 2014-07-22
- 发明人: Eastham Graham Ronald , Neil Tindale
- 申请人: Eastham Graham Ronald , Neil Tindale
- 申请人地址: GB
- 专利权人: Lucite International UK Limited
- 当前专利权人: Lucite International UK Limited
- 当前专利权人地址: GB
- 代理机构: Shumaker, Loop & Kendrick, LLP
- 优先权: GB0921875.1 20091215
- 国际申请: PCT/GB2010/052095 WO 20101215
- 国际公布: WO2011/073655 WO 20110623
- 主分类号: C07C67/38
- IPC分类号: C07C67/38
摘要:
A continuous process for carbonylation of ethylene in a liquid phase using carbon monoxide, a co-reactant and a suitable catalyst system, including: (i) forming a liquid phase comprising the co-reactant and a suitable catalyst system obtainable by combining: (a) a group VIII metal/compound; (b) a ligand of general formula (I) and c) optionally, a source of anions; wherein Q1 is optionally phosphorous; (ii) forming a gaseous phase in contact with the liquid phase by providing at least an ethylene gas input feed stream and a carbon monoxide gas input feed stream wherein the ethylene:CO molar ratio entering the liquid phase from the input feed streams is greater than 2:1; (iii) reacting ethylene with carbon monoxide in the presence of the co-reactant, and of the suitable catalyst system in the liquid phase; wherein the ethylene:CO gas molar ratio in the gaseous phase is between 20:1 and 1000:1 or wherein the molar ratio of ethylene:CO in the liquid phase is greater than 10:1.
公开/授权文献
- US20120277474A1 CONTINUOUS PROCESS FOR THE CARBONYLATION OF ETHYLENE 公开/授权日:2012-11-01