Invention Grant
- Patent Title: Oxidation process to produce a purified carboxylic acid product via solvent displacement and post oxidation
- Patent Title (中): 氧化工艺,通过溶剂置换和后氧化生产纯化的羧酸产物
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Application No.: US13553976Application Date: 2012-07-20
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Publication No.: US08809556B2Publication Date: 2014-08-19
- Inventor: Mesfin Ejerssa Janka , Kenny Randolph Parker , Paula Moody , Ashfaq Shaikh , Lee Reynolds Partin , Bradford Russell Bowers , Michael Charles Morrow
- Applicant: Mesfin Ejerssa Janka , Kenny Randolph Parker , Paula Moody , Ashfaq Shaikh , Lee Reynolds Partin , Bradford Russell Bowers , Michael Charles Morrow
- Applicant Address: US TN Kinsport
- Assignee: Eastman Chemical Company
- Current Assignee: Eastman Chemical Company
- Current Assignee Address: US TN Kinsport
- Agent Steven A. Owen
- Main IPC: C07D307/68
- IPC: C07D307/68

Abstract:
Disclosed is a process to produce a dry purified carboxylic acid product comprising furan-2,5-dicarboxylic acid (FDCA). The process comprises oxidizing at least one oxidizable compound to generate a crude carboxylic acid slurry comprising FDCA, removing impurities from a crude carboxylic acid slurry in a liquid displacement zone to form a low impurity slurry stream. The low impurity slurry stream is further treated in a secondary oxidation zone to produce a secondary oxidation slurry stream which is routed to a crystallization zone to form a crystallized slurry stream. The crystallized slurry stream is cooled in a cooling zone and the resulting cooled crystallized slurry stream is routed to a solid-liquid separation zone to generate a purified wet cake stream comprising FDCA that is dried in a drying zone to generate a dry carboxylic acid product stream comprising purified FDCA (pFDCA).
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