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US08809594B2 Dual catalyst system for the self-condensation of alcohols 有权
用于醇的自缩合的双催化剂体系

Dual catalyst system for the self-condensation of alcohols
Abstract:
Disclosed is a process for the production of higher aldehydes from lower alcohols using a two-stage vapor phase heterogeneous catalyst system. Ethanol feeds afford aldehydes such as butyraldehyde and crotonaldehyde while butanol feeds yield 2-ethylhexanal and 2-ethylhexenal. Higher product selectivities are obtained when the alcohol is first dehydrogenated in the upper catalyst stage followed by aldol condensation of the resulting lower aldehyde to a higher aldehyde.
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