Invention Grant
- Patent Title: Dual catalyst system for the self-condensation of alcohols
- Patent Title (中): 用于醇的自缩合的双催化剂体系
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Application No.: US13624035Application Date: 2012-09-21
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Publication No.: US08809594B2Publication Date: 2014-08-19
- Inventor: David William Norman , Damon Ray Billodeaux , Melissa Dawn Page
- Applicant: Eastman Chemical Company
- Applicant Address: US TN Kingsport
- Assignee: Eastman Chemical Company
- Current Assignee: Eastman Chemical Company
- Current Assignee Address: US TN Kingsport
- Agent Jennifer R. Knight
- Main IPC: C07C45/45
- IPC: C07C45/45 ; C07C29/141

Abstract:
Disclosed is a process for the production of higher aldehydes from lower alcohols using a two-stage vapor phase heterogeneous catalyst system. Ethanol feeds afford aldehydes such as butyraldehyde and crotonaldehyde while butanol feeds yield 2-ethylhexanal and 2-ethylhexenal. Higher product selectivities are obtained when the alcohol is first dehydrogenated in the upper catalyst stage followed by aldol condensation of the resulting lower aldehyde to a higher aldehyde.
Public/Granted literature
- US20140088326A1 DUAL CATALYST SYSTEM FOR THE SELF-CONDENSATION OF ALCOHOLS Public/Granted day:2014-03-27
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