发明授权
- 专利标题: Preparation of polypropylene in the presence of a single-site catalyst
- 专利标题(中): 在单中心催化剂存在下制备聚丙烯
-
申请号: US13516378申请日: 2010-06-16
-
公开(公告)号: US08829128B2公开(公告)日: 2014-09-09
- 发明人: Lauri Huhtanen , Kalle Kallio , Pascal Castro
- 申请人: Lauri Huhtanen , Kalle Kallio , Pascal Castro
- 申请人地址: AT Vienna
- 专利权人: Borealis AG
- 当前专利权人: Borealis AG
- 当前专利权人地址: AT Vienna
- 代理机构: Tarolli, Sundheim, Covell & Tummino LLP
- 优先权: EP09015854 20091222; EP09015898 20091222
- 国际申请: PCT/EP2010/058433 WO 20100616
- 国际公布: WO2011/076443 WO 20110630
- 主分类号: C08F4/642
- IPC分类号: C08F4/642 ; C08F4/6592 ; C08F10/06
摘要:
Process for the preparation of a polypropylene, wherein propylene is polymerized optionally with a comonomer selected from the group consisting of ethylene, a C4-C20 α-olefin and mixtures thereof, in the presence of a catalyst system comprising solid catalyst particles, wherein the solid catalyst particles (a) comprise a transition metal compound of formula (I) LmRnMXq (I) wherein “M” is a transition metal of anyone of the groups 3 to 10 of the periodic table (IUPAC), each “X” is independently a monovalent anionic σ-ligand, each “L” is independently an organic ligand which coordinates to the transition metal (M), each “R” is a bridging group linking two organic ligands (L), “m” is 2 or 3, preferably 2, “n” is 0, 1 or 2, preferably 1, “q” is 1, 2 or 3, preferably 2, m+q is equal to the valency of the transition metal (M), (c) comprise a cocatalyst (Co) comprising an element (E) of group 13 of the periodic table (IUPAC), preferably a cocatalyst (Co) comprising a compound of A1, wherein further the loss of activity of the solid catalyst particles during polymerization is at most 20%.
公开/授权文献
信息查询
IPC分类: