There is provided an austenitic stainless steel pipe excellent in steam oxidation resistance. The austenitic stainless steel pipe excellent in steam oxidation resistance contains, by mass percent, 14 to 28% of Cr and 6 to 30% of Ni, and is configured so that a region satisfying the following Formula exists in a metal structure at a depth of 5 to 20 μm from the inner surface of the steel pipe: (α/β)×δ/ε×100≧0.3 where the meanings of symbols in the above Formula are as follows: α: sum total of the number of pixels of digital image in region in which orientation difference of adjacent crystals detected by electron backscattering pattern is 5 to 50 degrees β: the number of total pixels of digital image in region of measurement using electron backscattering pattern ε: analysis pitch width of electron backscattering pattern (μm) δ: grain boundary width (μm).