Invention Grant
US08852517B2 Method for producing aliphatic polyester having increased molecular weight
有权
具有分子量增加的脂肪族聚酯的制造方法
- Patent Title: Method for producing aliphatic polyester having increased molecular weight
- Patent Title (中): 具有分子量增加的脂肪族聚酯的制造方法
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Application No.: US13997364Application Date: 2011-04-19
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Publication No.: US08852517B2Publication Date: 2014-10-07
- Inventor: Yasushi Ichikawa , Hideharu Kimura , Akira Ishii
- Applicant: Yasushi Ichikawa , Hideharu Kimura , Akira Ishii
- Applicant Address: JP Tokyo
- Assignee: Showa Denko K.K.
- Current Assignee: Showa Denko K.K.
- Current Assignee Address: JP Tokyo
- Agency: Wenderoth, Lind & Ponack, L.L.P.
- Priority: JP2010-288729 20101224
- International Application: PCT/JP2011/059604 WO 20110419
- International Announcement: WO2012/086226 WO 20120628
- Main IPC: B01J19/20
- IPC: B01J19/20 ; C08G18/42 ; C08G18/73 ; C08G18/08

Abstract:
The present invention addresses the problem of providing a method for continuously and effectively producing an aliphatic polyester having an increased molecular weight by preventing evaporation of a diisocyanate when blending the diisocyanate with an aliphatic polyester prepolymer in a molten state at a temperature not lower than the melting point thereof so that the diisocyanate and the aliphatic polyester prepolymer are uniformly blended.In order to solve the above-mentioned problem, the present invention provides a method for producing an aliphatic polyester having an increased molecular weight comprising the steps of (i) quantitatively injecting a diisocyanate into an aliphatic polyester prepolymer which has a number average molecular weight of 5,000 or higher and has terminal hydroxyl groups and in which at least one acid component is a succinic acid compound, in a melting state at a temperature not lower than the melting point thereof wherein the amount of the diisocyanate is equivalent to between one tenth and two times the amount of hydroxyl groups in the aliphatic polyester prepolymer, (ii) quantitatively and continuously introducing the diisocyanate-containing aliphatic polyester prepolymer obtained at the step (i) into a mixing tank, discharging same from the mixing tank under stirring and supplying it to a coupling reaction tank, and (iii) reacting the aliphatic polyester prepolymer with the diisocyanate in the coupling reaction tank.
Public/Granted literature
- US20130289221A1 METHOD FOR PRODUCING ALIPHATIC POLYESTER HAVING INCREASED MOLECULAR WEIGHT Public/Granted day:2013-10-31
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