An electro-conductive member for electrophotography, including an electro-conductive mandrel and an electro-conductive layer; and a process cartridge and an electrophotographic apparatus using the same. The layer contains a binder resin having a sulfo or a quaternary ammonium group as an ion exchange group, and an ion opposite in polarity to the ion exchange group. The resin has any one of structures represented by formulas (1)-1 and (1)-2, and any one of structures represented by formulas (2)-1 to (2)-3; and the resin has a molecular structure preventing occurrence of a matrix-domain structure. M represents an integer of 2-20, n represents an integer of 5-50, p represents an integer of 1-25, q represents an integer of 1-15, and r represents an integer of 1-12. —(CF2)m—  Formula (1)-1 —(CF2—CF2—O)n—  Formula (1)-2 —(CH2—CH2—O)p—  Formula (2)-1 —(CH2—CHCH3—O)q—  Formula (2)-2 —(CH2—CH2—CH2—CH2—O)r—  Formula (2)-3