This is to provide an all solid state secondary battery which can be produced by an industrially employable method capable of mass-production and has excellent secondary battery characteristics.This is an all solid state secondary battery containing a laminated material in which a positive-electrode unit and a negative-electrode unit are laminated alternately through an ion conductive inorganic-material layer, the positive-electrode unit has positive active material layers on both surfaces of a positive-electrode collector layer, the above-mentioned negative-electrode unit has negative active material layers on both surfaces of a negative-electrode collector layer, (A) at least one of the positive-electrode collector layer and the negative-electrode collector layer comprises a metal of either of Ag, Pd, Au and Pt, or an alloy containing either of Ag, Pd, Au and Pt, or a mixture containing two or more kinds selected from the metals and alloys, (B) each layer is in a sintered state, or (C) at least the starting material for the ion conductive inorganic material of the ion conductive inorganic-material layer is a calcined powder.