A method for orchestrating peer authentication during a call (e.g., a telephone call, a conference call between three or more parties, an instant messaging [IM] chat session, etc.) is disclosed. In particular, a user is first authenticated in order to participate in a call (e.g., via entering a password, etc.), and subsequently during the call the user may be peer authenticated. In accordance with the illustrative embodiment, a user who participates in a call might be prompted to authenticate another user on the call based on particular events or user behavior during the call.