发明授权
- 专利标题: Method for prolonging a catalyst's life during hydrofluorination
- 专利标题(中): 在氢氟化期间延长催化剂寿命的方法
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申请号: US12825040申请日: 2010-06-28
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公开(公告)号: US08952208B2公开(公告)日: 2015-02-10
- 发明人: Robert C. Johnson , Daniel C. Merkel
- 申请人: Robert C. Johnson , Daniel C. Merkel
- 申请人地址: US NJ Morristown
- 专利权人: Honeywell International Inc.
- 当前专利权人: Honeywell International Inc.
- 当前专利权人地址: US NJ Morristown
- 代理商 Bruce O. Bradford
- 主分类号: C07C17/00
- IPC分类号: C07C17/00 ; C07C17/25 ; C07C19/08 ; C07C21/18 ; C07C17/087 ; C07C17/20 ; C07C19/10
摘要:
The invention provides an improved process to manufacture 2-chloro-1,1,1,2-tetrafluoropropane (HCFC-244bb) by reacting 2-chloro-3,3,3,-trifluoropropene (HCFO-1233xf) with hydrogen fluoride, in the presence of a fluorination catalyst, where by using 2-chloro-3,3,3,-trifluoropropene (HCFO-1233xf) of high purity, the need to add an oxidizing agent (typically chlorine) to keep the catalyst active can be avoided. The HCFC-244bb is then used as an intermediate in the production of 2,3,3,3-tetrafluoropropene-1 (HFO-1234yf).
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