发明授权
US08957134B2 Method of preparing encapsulated pigment dispersions with minimal free polymer
有权
用最小游离聚合物制备包封的颜料分散体的方法
- 专利标题: Method of preparing encapsulated pigment dispersions with minimal free polymer
- 专利标题(中): 用最小游离聚合物制备包封的颜料分散体的方法
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申请号: US14117897申请日: 2011-12-15
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公开(公告)号: US08957134B2公开(公告)日: 2015-02-17
- 发明人: Hee Hyun Lee , Michael Joseph Otley , Michael Stephen Wolfe , Tristan Williams
- 申请人: Hee Hyun Lee , Michael Joseph Otley , Michael Stephen Wolfe , Tristan Williams
- 申请人地址: US DE Wilmington
- 专利权人: E I du Pont de Nemours and Company
- 当前专利权人: E I du Pont de Nemours and Company
- 当前专利权人地址: US DE Wilmington
- 代理商 Simon L. Xu
- 国际申请: PCT/US2011/065111 WO 20111215
- 国际公布: WO2013/009342 WO 20130117
- 主分类号: C09D11/10
- IPC分类号: C09D11/10 ; C09C3/10 ; C08G18/08 ; C08G18/12 ; C08G18/34 ; C08G18/44 ; C08G18/66 ; C08G18/76 ; C09D11/322 ; C09D175/04 ; C09B67/08 ; C09D11/326 ; C08L33/10
摘要:
A process for encapsulating pigment dispersions is provided where a pigment is dispersed with a polymeric dispersant in an aqueous solvent system. The free polymer dispersant in the pigment dispersion is limited to less than 0.12 grams per gram of pigment. This dispersed pigment is then encapsulated by adding acrylate monomers and optionally acrylic and vinyl monomers and polymerizing. In the encapsulated pigment dispersion the weight ratio of final free polymer to polymer found to the final encapsulated pigment is less than 0.9. The free polymer dispersant is measured by a centrifugation method and the final free polymer is measured by a density gradient centrifugation method. Such encapsulated pigment dispersions may be used in inkjet inks and are stable to heat, aging test conditions, and solvent challenges. Prints from these inks have better durability.
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