发明授权
- 专利标题: Method for mechanically stabilizing nitrogen-containing polymers
- 专利标题(中): 机械稳定含氮聚合物的方法
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申请号: US13509432申请日: 2010-11-12
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公开(公告)号: US09006300B2公开(公告)日: 2015-04-14
- 发明人: Oliver Gronwald , Jörg Belack , Jochen Baurmeister , Thomas Justus Schmidt , Seongwoo Choi , Jung Ock Park , Woo Sung Jeon , Jung Seok Yi
- 申请人: Oliver Gronwald , Jörg Belack , Jochen Baurmeister , Thomas Justus Schmidt , Seongwoo Choi , Jung Ock Park , Woo Sung Jeon , Jung Seok Yi
- 申请人地址: KR Gyeonggi-Do
- 专利权人: Samsung Electronics Co., Ltd.
- 当前专利权人: Samsung Electronics Co., Ltd.
- 当前专利权人地址: KR Gyeonggi-Do
- 代理机构: Drinker Biddle & Reath LLP
- 优先权: EP09014252 20091114
- 国际申请: PCT/EP2010/006912 WO 20101112
- 国际公布: WO2011/057804 WO 20110519
- 主分类号: H01M8/10
- IPC分类号: H01M8/10 ; C08J5/22 ; C08L79/06 ; C08L29/04 ; H01M8/02
摘要:
A method for the production of a mechanically stabilized polyazole polymer membrane or film having the following steps: a) providing a membrane or film containing i.) a polyazole with at least one amino group in a repeating unit except the ones obtained by reacting aromatic and/or heteroaromatic diaminocarboxylic acids, ii.) at least one strong acid and iii.) at least one stabilizing reagent, the total content of stabilizing reagents in the membrane or film being within the range of from 0.01 to 30% by weight, b) performing the stabilization reaction in the membrane, immediately or in a subsequent processing step of the membrane, c) optionally doping the membrane obtained in accordance with step b) with a strong acid or concentrating the present strong acid by removal of present water, wherein the stabilizing reagent contains at least one oxazine-based compound and wherein the polyazole polymer has at least 1.8 dl/g intrinsic viscosity.