发明授权
- 专利标题: Zeolite separation membrane, method for producing the same, and bonding agent
- 专利标题(中): 沸石分离膜,其制造方法和粘合剂
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申请号: US12998221申请日: 2008-10-01
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公开(公告)号: US09022226B2公开(公告)日: 2015-05-05
- 发明人: Kazuhiro Yano , Yoshinobu Takaki
- 申请人: Kazuhiro Yano , Yoshinobu Takaki
- 申请人地址: JP Osaka-shi
- 专利权人: Hitachi Zosen Corporation
- 当前专利权人: Hitachi Zosen Corporation
- 当前专利权人地址: JP Osaka-shi
- 代理机构: Locke Lord LLP
- 代理商 James E. Armstrong, IV
- 国际申请: PCT/JP2008/067797 WO 20081001
- 国际公布: WO2010/038281 WO 20100408
- 主分类号: B01D71/02
- IPC分类号: B01D71/02 ; B01D69/04 ; B32B37/06 ; C04B35/14 ; B01D65/00 ; B01D63/06 ; B01D69/10 ; C04B35/117 ; C04B37/00 ; C04B38/00 ; C03C8/04 ; C03C8/24 ; C04B111/00
摘要:
A separation membrane according to the present invention is characterized by having a porous tube containing an alumina as a main component and an attachment member disposed in a connection position of the porous tube, wherein the porous tube and the attachment member are bonded by a ceramic oxide-based bonding agent containing 17 to 48 wt % of SiO2, 2 to 8 wt % of Al2O3, 24 to 60 wt % of BaO, and 0.5 to 5 wt % of ZnO as essential components and containing at least one of La2O3, CaO, and SrO, and a thin zeolite layer is formed on a surface of the porous tube. The attachment member is bonded to the porous tube before the formation of the zeolite layer. Therefore, the bonding agent can have a melting temperature higher than 600° C., which is the upper heatproof temperature limit of the zeolite. Thus, the ceramic oxide material for the bonding agent can be selected from a wider range of compositions such as glass compositions (without limitations on the glass softening temperature).
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