A liquid crystal display device includes a first substrate, a first electrode on the first substrate, a second substrate facing the first substrate, a second electrode on the second substrate facing the first electrode, and a liquid crystal structure between the first electrode and the second electrode. The liquid crystal structure includes a polymer network and liquid crystal molecules. The liquid crystal display device operates in a transmissive mode when an electric field is not generated between the first and the second electrodes, and operates in a scattering mode when the electric field is generated between the first and the second electrodes.