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US09074026B2 Polyisobutylene prepared with low diluent content reaction medium 有权
聚异丁烯用低稀释剂制备反应介质

  • Patent Title: Polyisobutylene prepared with low diluent content reaction medium
  • Patent Title (中): 聚异丁烯用低稀释剂制备反应介质
  • Application No.: US14347695
    Application Date: 2012-10-10
  • Publication No.: US09074026B2
    Publication Date: 2015-07-07
  • Inventor: Sohel K. Shaikh
  • Applicant: TPC Group LLC
  • Applicant Address: US TX Houston
  • Assignee: TPC GROUP LLC
  • Current Assignee: TPC GROUP LLC
  • Current Assignee Address: US TX Houston
  • Agent Michael W. Ferrell
  • International Application: PCT/US2012/059489 WO 20121010
  • International Announcement: WO2013/062763 WO 20130502
  • Main IPC: C08F2/00
  • IPC: C08F2/00 C08F2/02 C08F2/14 C08F110/10
Polyisobutylene prepared with low diluent content reaction medium
Abstract:
A method of making a polyisobutylene polymer in a recirculating loop reactor with one or more reaction tubes in contact with a heat transfer medium includes: (a) providing a feed mixture consisting essentially of polymerizable monomer and catalyst to a residual reactor stream at a feed rate to form a reaction mixture, the reaction mixture containing less than 5% by weight diluent components; (b) recirculating the reaction mixture in the one or more reaction tubes of the loop reactor at a recirculation rate greater than the feed rate utilizing a recirculating pump operating at a pressure differential, delta P, corresponding to a recirculating flow; (c) polymerizing the reaction mixture in the one or more tubes of the loop reactor to convert the feed mixture to polyisobutylene polymer while cooling the one or more tubes of the loop reactor with the heat transfer medium; and (e) withdrawing polyisobutylene polymer from the loop reactor.
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