A photoluminescent material has the characteristic of a long photoluminescence decay and has the general composition Ca3-x-m-nAxSc2-yMySi3-zEzO12:mCe3+,nMn2+, where A is at least one divalent cation including Sr, Ba or a combination of monovalent and trivalent cations including combinations of Li, Na, K, B, Al and Ga; M is at least one trivalent cation including Al, Ga, or a divalent cation including Mg, E is a combination of a trivalent and a pentavalent cation including B, Al, Ga, N and P, or a combination of monovalent and trivalent cations including Li, Na, K, B, Al, Ga, N and P. The A cation replaces Ca; the M cation replaces Sc, and E replaces Si. This Mn and Ce doped phosphor emits in the yellow to green with a peak at around 510 and/or 560 and 690 nm. The phosphor material has applications in LED illumination systems.