A portable communication apparatus and a method for establishing a wireless connection thereof are provided. The method is adapted to the portable communication apparatus establishing the wireless connection with at least one peripheral apparatus by using a first wireless communication module and a second wireless communication module, in which a signal range of the first wireless communication module is larger than that of the second wireless communication module. In the present method, at least one peripheral apparatus located within the signal range of the first wireless communication module is searched by using the first wireless communication module, and a first wireless connection with the searched peripheral apparatus is established. Next, state information of a corresponding second wireless communication on each peripheral apparatus is obtained through the first wireless connection. Then, a second wireless connection with the at least one apparatus is established by using the second wireless communication module.