发明授权
- 专利标题: Method for producing ethylene glycol from oxalate through the fluidized bed catalytic reaction
- 专利标题(中): 通过流化床催化反应从草酸生产乙二醇的方法
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申请号: US14000876申请日: 2012-02-24
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公开(公告)号: US09102583B2公开(公告)日: 2015-08-11
- 发明人: Weimin Yang , Juntao Liu , Wanmin Wang , Jun Kuai
- 申请人: Weimin Yang , Juntao Liu , Wanmin Wang , Jun Kuai
- 申请人地址: CN Beijing CN Shanghai
- 专利权人: CHINA PETROLEUM & CHEMICAL CORPORATION,SHANGHAI RESEARCH INSTITUTE OF PETROCHEMICAL TECHNOLOGY, SINOPEC
- 当前专利权人: CHINA PETROLEUM & CHEMICAL CORPORATION,SHANGHAI RESEARCH INSTITUTE OF PETROCHEMICAL TECHNOLOGY, SINOPEC
- 当前专利权人地址: CN Beijing CN Shanghai
- 代理机构: Buchanan Ingersoll & Rooney PC
- 优先权: CN201110045356 20110225; CN201110045364 20110225
- 国际申请: PCT/CN2012/000236 WO 20120224
- 国际公布: WO2012/113267 WO 20120830
- 主分类号: C07C27/04
- IPC分类号: C07C27/04 ; C07C29/149 ; B01J23/83 ; B01J23/84 ; B01J23/843 ; B01J23/888 ; B01J29/48
摘要:
A process for producing ethylene glycol includes contacting an oxalate with a fluidized bed catalyst under the following conditions: a reaction temperature of from about 170 to about 270° C., a weight space velocity of oxalate of from about 0.2 to about 7 hours−1, a hydrogen/ester molar ratio of about 20˜200:1, a reaction pressure of from about 1.5 to about 10 MPa, and a reaction temperature difference T of from about 1 to about 15° C. The fluidized bed catalyst includes: a) from about 5 to about 80 parts by weight of copper and the oxide thereof, b) from about 10 to about 90 parts by weight of at least one carrier selected from silica, molecular sieve or alumina, c) from about 0.01 to about 30 parts by weight of bismuth and tungsten metallic elements or the oxides thereof, or cerium and niobium metallic elements or the oxides thereof.
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