The present invention provides a device and system for desorption and dehumidification, comprising a conductive electrode, a moisture absorber, and a power source. The conductive electrode comprises a first surface and a second surface opposite to the first surface, and the first surface has a plurality of protrusion elements. The moisture absorber comprises a third surface formed on the plurality of protrusions. The power source provides power to the conductive electrode such that a uniform and stable micro-discharge phenomenon is generated thereby forming a continuous charge flow. The continuous charge flow can further generate an electrical interruption for depolarizing the attraction between the moisture molecules and moisture absorber whereby the moisture molecules can be desorbed from the moisture absorber more easily.