发明授权
- 专利标题: Method for synthesizing rare earth metal extractant
- 专利标题(中): 稀土金属萃取剂的合成方法
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申请号: US13808220申请日: 2011-07-01
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公开(公告)号: US09133100B2公开(公告)日: 2015-09-15
- 发明人: Kazuaki Sakaki , Hiroto Sugahara , Tetsuya Kume , Masaki Ohashi , Hirochika Naganawa , Kojiro Shimojo
- 申请人: Kazuaki Sakaki , Hiroto Sugahara , Tetsuya Kume , Masaki Ohashi , Hirochika Naganawa , Kojiro Shimojo
- 申请人地址: JP Tokyo JP Ibaraki
- 专利权人: SHIN-ETSU CHEMICAL CO., LTD.,JAPAN ATOMIC ENERGY AGENCY
- 当前专利权人: SHIN-ETSU CHEMICAL CO., LTD.,JAPAN ATOMIC ENERGY AGENCY
- 当前专利权人地址: JP Tokyo JP Ibaraki
- 代理机构: Westerman, Hattori, Daniels & Adrian, LLP
- 优先权: JP2010-153180 20100705
- 国际申请: PCT/JP2011/065172 WO 20110701
- 国际公布: WO2012/005182 WO 20120112
- 主分类号: C07C229/00
- IPC分类号: C07C229/00 ; C07C231/02 ; C07C235/06 ; C22B47/00 ; C22B59/00 ; C22B3/08 ; C22B3/44
摘要:
A rare earth metal extractant containing, as the extractant component, dialkyldiglycol amide acid which is excellent in breaking down light rare earth elements is reacted in diglycolic acid (X mol) and an esterification agent (Y mol) at a reaction temperature of 70° C. or more and for a reaction time of one hour or more such that the mol ratio of Y/X is 2.5 or more, and is subjected to vacuum concentration. Subsequently, a reaction intermediate product is obtained by removing unreacted products and reaction residue. Then a nonpolar or low-polar solvent which is an organic solvent for forming an organic phase during solvent extraction of the rare earth metal and which is capable of dissolving dialkyldiglycol amide acid is added as the reaction solvent, and the reaction intermediate product is reacted with dialkyl amine (Z mol) such that the mol ratio of Z/X is 0.9 or more.
公开/授权文献
- US20130123534A1 METHOD FOR SYNTHESIZING RARE EARTH METAL EXTRACTANT 公开/授权日:2013-05-16
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