发明授权
- 专利标题: Production methods for solubilized lignin, saccharide raw material and monosaccharide raw material, and solubilized lignin
- 专利标题(中): 溶解木质素,糖原料和单糖原料以及溶解木质素的生产方法
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申请号: US12682377申请日: 2008-10-15
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公开(公告)号: US09133227B2公开(公告)日: 2015-09-15
- 发明人: Jun-ichi Azuma , Tetsuo Sakamoto , Kiyotaka Onishi
- 申请人: Jun-ichi Azuma , Tetsuo Sakamoto , Kiyotaka Onishi
- 申请人地址: JP Tokyo
- 专利权人: NIPPON STEEL & SUMIKIN CHEMICAL CO., LTD.
- 当前专利权人: NIPPON STEEL & SUMIKIN CHEMICAL CO., LTD.
- 当前专利权人地址: JP Tokyo
- 代理机构: Kratz, Quintos & Hanson, LLP
- 优先权: JP2007-269704 20071017
- 国际申请: PCT/JP2008/002912 WO 20081015
- 国际公布: WO2009/050882 WO 20090423
- 主分类号: D21C1/00
- IPC分类号: D21C1/00 ; C07G1/00 ; C07H3/02
摘要:
A new lignin degradation product, a method for producing the same, and methods for producing a saccharide raw material and a monosaccharide raw material are provided.The method for producing the new lignin degradation product includes: (a first step) mixing 100 parts by mass of a powder, obtained by pulverizing a lignocellulosic raw material and defatting the resulting powder with an organic solvent, with aqueous hydrogen peroxide in an amount of 20 to 400 parts by mass in terms of hydrogen peroxide and heating the mixture for 5 to 120 minutes at a pressure of 0.1 to 1.5 MPa and a temperature of 80 to 200° C. while irradiating the mixture with microwaves; (a second step) separating insoluble matter from the aqueous hydrogen peroxide; (a third step) extracting the insoluble matter with a solvent to produce an extract; and (a fourth step) distilling the solvent away from the extract to yield a solubilized lignin as a residue. Further, a saccharide raw material composed mainly of a polysaccharide or a monosaccharide raw material is obtained by subjecting the liquid portion or the insoluble matter, respectively, obtained in the first step to a predetermined treatment.
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