发明授权
US09206507B2 Nickel bis diazabutadiene precursors, their synthesis, and their use for nickel containing films depositions 有权
镍二氮杂二烯前体,它们的合成及其在含镍膜沉积中的用途

Nickel bis diazabutadiene precursors, their synthesis, and their use for nickel containing films depositions
摘要:
Disclosed are homoleptic diazabutadiene nickel precursors used for the vapor deposition of nickel-containing films. The precursors have the general formula Ni(R-DAD)2, wherein R-DAD stands for substituted 1,4-diazabuta-1,3-diene ligands. The sole presence of the Ni—N bonds was also considered to avoid too high intrusion of other elements, such as carbon, into the nickel-containing films. The flexibility of the Ni—N bond in terms of film deposition also allows using the molecules for nickel, nickel-nitride, nickel-carbonitride, nickel oxide or any other type of nickel-containing films. The nickel-containing film depositions can be carried out by thermal and/or plasma-enhanced CVD, ALD, and pulse CVD or any other type of depositions methods.
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