发明授权
US09243099B2 Low vinyl styrene-butadiene polymers and methods of making the same
有权
低乙烯基苯乙烯 - 丁二烯聚合物及其制备方法
- 专利标题: Low vinyl styrene-butadiene polymers and methods of making the same
- 专利标题(中): 低乙烯基苯乙烯 - 丁二烯聚合物及其制备方法
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申请号: US13702685申请日: 2011-06-15
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公开(公告)号: US09243099B2公开(公告)日: 2016-01-26
- 发明人: Silvia Valenti , Evemarie Hamann
- 申请人: Silvia Valenti , Evemarie Hamann
- 申请人地址: CH Horgen
- 专利权人: TRINSEO EUROPE GMBH
- 当前专利权人: TRINSEO EUROPE GMBH
- 当前专利权人地址: CH Horgen
- 代理机构: Brinks Gilson & Lione
- 国际申请: PCT/EP2011/059918 WO 20110615
- 国际公布: WO2011/157742 WO 20111222
- 主分类号: C08L9/06
- IPC分类号: C08L9/06 ; C08F236/10 ; C08F212/08
摘要:
The invention provides a process for the continuous polymerization of a polymer comprising monomeric units derived from styrene and 1,3-butadiene, said process comprising: polymerizing the monomers in the presence of an initiator, and at least one polar agent selected from Formula 1; wherein R1 and R2 are each independently an alkyl, and preferably a C1-C4 alkyl; R3, R4, R5, R6, R7 and R8 are each independently selected from hydrogen or an alkyl, and preferably hydrogen or a C1-C4 alkyl; and wherein a 1,2-diene is added to the polymerization, and the 1,2-diene to active initiator (active for polymerization) molar ratio is from 0.1 to 1.0, preferably from 0.1 to 0.9, and more preferably from 0.1 to 0.85; and wherein the polar agent to the active initiator molar ratio is from 0.05 to 0.6, preferably from 0.1 to 0.5, more preferably from 0.15 to 0.3. The invention also provides a composition comprising a polymer comprising monomeric units derived from styrene and 1,3-butadiene, and wherein the polymer has at least the following characteristics: A) vinyl content from 12 to 40 weight percent, based on the weight of polymerized butadiene in the polymer, B) block styrene content less than 8 weight percent, based on the weight of styrene in the polymer, and C) a styrene content from 10 to 50 weight percent, based on the weight of the polymer.
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