The present disclosure relates to the technical field of light emission of an LED and discloses a light emitting diode assembly, a backlight module, a liquid crystal display and an illumination device. The LED assembly comprises a lamp base and at least one pair of LED dies. The lamp base has a mounting groove. A pair of the LED dies are mounted at a bottom surface of the mounting groove, and two LED dies in the pair of LED dies are disposed symmetrically about an axis of the mounting groove. Among angles formed by intersection of planes where light exit surfaces of the two LED dies lie, an angle facing the bottom surface of the mounting groove is greater than 0 degree and less than 180 degrees. The light emitting diode assembly has a larger light exit angle and exhibits a simple structure.