Invention Grant
US09266850B2 Oxidation process to produce a purified carboxylic acid product via solvent displacement and post oxidation 有权
氧化工艺,通过溶剂置换和后氧化生产纯化的羧酸产物

Oxidation process to produce a purified carboxylic acid product via solvent displacement and post oxidation
Abstract:
Disclosed is a process to produce a dry purified carboxylic acid product comprising furan-2,5-dicarboxylic acid (FDCA). The process comprises oxidizing at least one oxidizable compound selected from the following group: 5-(hydroxymethyl)furfural (5-HMF), 5-HMF esters (5-R(CO)OCH2-furfural where R is alkyl, cycloalkyl, or aryl), 5-HMF ethers (5-R′OCH2-furfural where R′ is alkyl, cycloalkyl, or aryl), 5-alkyl furfurals (5-R″-furfural where R″ is alkyl, cycloalkyl, or aryl), mixed feedstocks of 5-HMF and 5-HMF esters, mixed feedstocks of 5-HMF and 5-HMF ethers, and mixed feedstocks of 5-HMF and 5-alkyl furfurals to generate a crude carboxylic acid slurry comprising FDCA.
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