Invention Grant
- Patent Title: Oxidation process to produce a purified carboxylic acid product via solvent displacement and post oxidation
- Patent Title (中): 氧化工艺,通过溶剂置换和后氧化生产纯化的羧酸产物
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Application No.: US14692416Application Date: 2015-04-21
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Publication No.: US09266850B2Publication Date: 2016-02-23
- Inventor: Mesfin Ejerssa Janka , Kenny Randolph Parker , Paula Moody , Ashfaq Shahanawaz Shaikh , Lee Reynolds Partin , Bradford Russell Bowers , Michael Charles Morrow
- Applicant: Eastman Chemical Company
- Applicant Address: US TN Kingsport
- Assignee: Eastman Chemical Company
- Current Assignee: Eastman Chemical Company
- Current Assignee Address: US TN Kingsport
- Agency: Phan Law Group PLLC
- Main IPC: C07D307/68
- IPC: C07D307/68 ; C07D307/60

Abstract:
Disclosed is a process to produce a dry purified carboxylic acid product comprising furan-2,5-dicarboxylic acid (FDCA). The process comprises oxidizing at least one oxidizable compound selected from the following group: 5-(hydroxymethyl)furfural (5-HMF), 5-HMF esters (5-R(CO)OCH2-furfural where R is alkyl, cycloalkyl, or aryl), 5-HMF ethers (5-R′OCH2-furfural where R′ is alkyl, cycloalkyl, or aryl), 5-alkyl furfurals (5-R″-furfural where R″ is alkyl, cycloalkyl, or aryl), mixed feedstocks of 5-HMF and 5-HMF esters, mixed feedstocks of 5-HMF and 5-HMF ethers, and mixed feedstocks of 5-HMF and 5-alkyl furfurals to generate a crude carboxylic acid slurry comprising FDCA.
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