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US09266980B2 Polyisobutylene prepared at high velocity and circulation rate 有权
聚异丁烯以高速度和循环速率制备

Polyisobutylene prepared at high velocity and circulation rate
Abstract:
A method of making a polyisobutylene polymer in a recirculating loop reactor with one or more reaction tubes in contact with a heat transfer medium includes controlling the delta P and polymerization reaction to provide a linear velocity of the reaction mixture of at least 11 ft/sec in the one or more tubes of the loop reactor and/or controlling the delta P and polymerization reaction of steps (b) and (c) to provide a recirculation ratio of the recirculation rate to the feed rate of at least 30:1. Typically, the process utilizes a recirculating pump operating at a pressure differential of from 35 psi to 70 psi.
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