An engine system is provided. The engine system includes an ambient condition module configured to generate a signal indicative of a state of ambient air. The engine system also includes an operational parameter sensor configured to generate a signal indicative of one or more operational parameters associated with the engine. The engine system further includes a controller communicably coupled to the ambient condition module and the operational parameter sensor. The controller is configured to receive the signal indicative of the pressure of ambient air and the signal indicative of the one or more operational parameters associated with the engine. The controller estimates the temperature of at least one of a valve, a piston, a liner, a cylinder head, and a pre-chamber of the engine as a function of the received signals and parameters associated with fuel delivery to the engine.