A docking station for a portable electronic device is provided. The docking station includes a main body, a supporting structure and a pivot. The pivot includes a first fixing portion, a second fixing portion and a pivot portion. The first fixing portion is disposed at the supporting structure, the second fixing portion is disposed at the main body. The pivot portion is connected to the first fixing portion and the second fixing portion. When the portable electronic device is disposed at the supporting structure, the portable electronic device and the supporting structure can rotate relative to the main body via the pivot. The docking station allows the portable electronic device disposing at the docking station drives the supporting structure to rotate relatively to the main body alone the axis of the pivot to stand in vertical, and then the horizontal space of the portable electronic device is saved.