Disclosed are an apparatus and a method for analyzing a distribution of electromagnetic waves using a 4-port transverse electromagnetic (TEM) cell in a radio wave system. The apparatus for analyzing a distribution of electromagnetic waves in a radio wave system includes: an input unit configured to apply a reference electrostatic potential to an inside of a 4-port transverse electromagnetic (TEM) cell in which electronic devices are located; a calculation unit configured to calculate electrostatic potentials inside the 4-port TEM cell using a mode matching scheme; an analysis unit configured to analyze the distribution of electromagnetic waves inside the 4-port TEM cell through the electrostatic potentials inside the 4-port TEM cell; and an output unit configured to output the distribution of electromagnetic waves inside the 4-port TEM cell.