Invention Grant
- Patent Title: Process for the production of alkyl ethers by the etherification of isobutene
- Patent Title (中): 通过异丁烯醚化生产烷基醚的方法
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Application No.: US12373730Application Date: 2007-07-12
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Publication No.: US09403744B2Publication Date: 2016-08-02
- Inventor: Marco Di Girolamo , Massimo Conte , Antonio Sgambati , Alberto Cipelli
- Applicant: Marco Di Girolamo , Massimo Conte , Antonio Sgambati , Alberto Cipelli
- Applicant Address: IT San Donato Milanese
- Assignee: SAIPEM S.p.A.
- Current Assignee: SAIPEM S.p.A.
- Current Assignee Address: IT San Donato Milanese
- Agency: Oblon, McClelland, Maier & Neustadt, L.L.P.
- Priority: ITMI2006A1390 20060718
- International Application: PCT/EP2007/006307 WO 20070712
- International Announcement: WO2008/009409 WO 20080124
- Main IPC: C07C41/01
- IPC: C07C41/01 ; C07C41/06

Abstract:
Process for the production of alkyl ethers by the etherification of isobutene, contained in C4-C5 hydrocarbon streams, with linear alcohol, in the presence of acid catalysts, comprising the following essential steps: a) feeding the isobutene contained in C4-C5 hydrocarbon cuts, together with one or more streams containing linear alcohol, to a first reaction step; b) sending the stream leaving the first reaction step to a first distillation area, separating a light stream from a heavy stream containing the desired ether; c) feeding the light stream separated in the first distillation area, together with one or more streams containing linear alcohol, to a second reaction step; d) sending the stream leaving the second reaction step to a second distillation area separating a light stream from a heavy stream containing ether, C4 hydrocarbons and alcohol which is recycled to the first distillation area; e) sending the light stream in the second distillation area to a recovery section of the linear alcohol contained therein; f) recycling the linear alcohol recovered in the recovery section to at least one of the two reaction steps. The present invention relates to plant solutions which allow the alcohol/isobutene molar ratio to be increased in the reaction steps and therefore maximizing the conversion of isobutene.
Public/Granted literature
- US20090253942A1 PROCESS FOR THE PRODUCTION OF ALKYL ETHERS BY THE ETHERIFICATION OF ISOBUTENE Public/Granted day:2009-10-08
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