To provide a cellulose acylate film having low moisture permeability and low haze, a polarizing plate, and a liquid crystal display device using the same. A cellulose acylate film comprising at least a cellulose acylate, and a compound represented by the formula (1) below: in the formula (1), R1 represents a hydrogen atom or substituent, R2 represents a substituent represented by the formula (2) below; n1 represents an integer of 0 to 4, when n1 is 2 or larger, the plurality of (R1)s may be same with or different from each other; n2 represents an integer of 1 to 5, when n2 is 2 or larger, the plurality of (R2)s may be same with or different from each other.